The Opening Ceremony will be produced by Russia's Channel One and the "creative concept" will be developed by Felix Mikhailov, who has directed other World Cup events including the preliminary and main draw.
The Ceremony will focus on musical acts and take place just 30 minutes before kick-off scheduled for 6pm local time.
Neymar and co. are backed to lift the trophy for a record-extending sixth time by 43 percent of users on the day before the tournament kicks off in Moscow on June 14.
The opening ceremony will take place at 5:30 p.m. local time (10:30 a.m. ET), just 30 minutes before Russian Federation and Saudi Arabia spar off to officially commence this year's World Cup.
The action gets underway on Thursday when hosts Russian Federation face Saudi Arabia in Moscow.
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Federation Internationale de Football Association did not comment on whether the song would form part of Williams' performance, saying the set list would be kept as a "surprise".
"A year later in 2017, he was involved in another semi-final, in the FIFA Confederations Cup between Germany and Mexico".
At the end of its technical meeting ahead of the World Cup finals which gets underway this week in Russia, FIFA announced that changes will be made to the way that the world rankings of global teams are calculated, switching to a method that add or subtracts points from a country's total rather than averaging them over a multi-year period.
Sepp Blatter, the disgraced former president of Federation Internationale de Football Association whose dramatic fall from power corresponded with revelations of widespread corruption among the organisation's top officials, will attend the World Cup in Russia as a personal guest of President Vladimir Putin. "In a World Cup, any small thing can knock you out", the legendary midfielder told Cadena Cope.